Product ID:GASOLINE, LEADED/UNLEADED (ALL GRADES)
MSDS Date:03/01/1988
FSC:9130
NIIN:00-264-6216
MSDS Number: BQNCB

KOCK REFINING CO INC

SUNTIDE RD
CORPUS CHRISTI, TX 78403
US

Emergency Phone: 512-241-4811

Info Phone: 512-241-4811 / FAX 512-289-8470

Preparer: DALE F. JANES

Cage: KO284

KOCK REFINING CO INC

2608 CORPUS CHRISTI, TX 78403 US

Telephone: 512-241-4811 / FAX 512-289-8470

Cage: KO284

GASOLINE - PRODUCT MIXTURE CONTAINING THE FOLLOWING

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

PARAFFINS (MIX)

Fraction By Weight: 46%

OLEFIN(S)

CAS: 68425-39-8

Fraction By Weight: 17%

NAPHTHENES

Fraction By Weight: 8%

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1.5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

AROMATICS (OTHER)

Fraction By Weight: 27%

LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: MODERATE RISK OF VAPOR
INTOXICATION. MAJOR RISK IS ENCLOSED SPACES WITH POOR VENTILATION.
SKIN: DEFATTING WITH DRYING AND CRACKING CAN LEAD TO DERMATITIS AND
SECONDARY INFECTION. EYE: IRRI TANT. INGESTION: BURNING OF MOUTH
AND UPPER GI TRACT, VOMITING AND DIARRHEA. PROLONGED OR REPEATED
CONTACT: DERMATITIS.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:INHALATION MAY CAUSE EUPHORIA, LUNG IRRITATION
AND EDEMA, HEADACHE, DIZZINESS, DROWSINESS, CONVULSIONS, COMA,
CYANOSIS, GENERALIZED DEPRESSION. INGESTION MAY CAUSE GENERAL
DEPRESSION, SEDATION, RESPIR ATORY DEPRESSION, COMA.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING
DERMATITIS, RESPIRATORY ILLNESS, OR OTHER CONDITIONS WHICH HAVE THE
SAME SYMPTOMS OR EFFECTS AS STATED ABOVE.

First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH
SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. FOR RESPIRATORY
DISTRESS, GIVE AIR, OXYGEN, OR CPR IF NECESSARY. INGESTION: DO NOT
INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS TO PREVENT
ASPIRATION INTO LUNGS. GET MEDICAL ATTENTION IF REQUIRED IN ALL
CASES.

Flash Point Method:TCC
Flash Point:-40F,-40C
Autoignition Temp:Autoignition Temp Text:>536F
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES, BUT SHOULD
BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL. WATER SPRAY MAY BE
USED TO FLUSH SPILL AWAY FROM AREAS OF IGINTION.
Unusual Fire/Explosion Hazard:HIGHLY VOLATILE MATERIAL. FLOWING
GASOLINE CAN BE IGNITED BY SELF-GENERATED STATIC ELECTRICITY.
VAPORS MAY TRAVEL ALONG THE GROUND TO A REMOTE IGNITION SOURCE.

Spill Release Procedures:SMALL: TAKE UP WITH NON COMBUSTIBLE ABSORBENT
SUCH AS FULLERS EARTH OR SAND. PLACE INTO CONTAINERS FOR LATER
DISPOSAL. LARGE: CONTAIN SPILL IN EARTHEN DIKES FOR LATER RECOVERY.
CONTROL IGNITION SOURCE S AROUND SPILL AREA. REPORT SPILLS AS
REQUIRED.

Handling and Storage Precautions:AVOID STATIC IGNITION HAZARD WHEN
TRANSFERRING MATERIAL. KEEP CONTAINERS CLOSED AND AWAY FROM HEAT &
IGNITION SOURCES! DO NOT USE AS CLEANING AGENT.
Other Precautions:EMPTY CONTAINERS RETAIN SOME LIQUID/VAPOR RESIDUES;
HAZARD PRECAUTIONS MUST BE OBSERVED WHEN HANDLING EMPTIES. KEEP OUT
OF REACH OF CHILDREN! DO NOT USE ANY HYDROCARBON FUEL IN SPACES
WITHOUT ADEQUATE VENTILATION. USE ONLY AS A FUEL.

Respiratory Protection:A NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR,
SUPPLIED AIR, OR SELF-CONTAINED BREATHING APPARATUS (SCBA) MUST BE
USED WHEN VAPOR CONCENTRATIONS EXCEED THE OCCUPATIONAL EXPOSURE
LIMITS.
Ventilation:USE ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF
THIS MATERIAL BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:WEAR OIL IMPERVIOUS (EG: NITRILE) GLOVES
Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:OIL IMPERVIOUS INDUSTRIAL WORK CLOTHING TO
MINIMIZE SKIN CONTACT. EYE BATH AND SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. USE WATERLESS HAND
CLEANER TO WASH EXPOSED SKIN. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
THE VARIABLE COMPOSITION MAKES IT IMPOSSIBLE TO SET A SPECIFIC EXPOSURE
LIMIT FOR ALL COMPOSITIONS OF THIS MATERIAL. SPECIFIC EXPOSURE
LIMITS FOR POTENTIAL COMPONENTS SUCH AS BENZENE SHOULD BE APPLIED
BASED ON AIR MONITORING TO ASSURE EMPLOYEES ARE NOT EXPOSED TO
EXCESSIVE VAPOR LEVELS OF COMPONENTS.

HCC:F1
Boiling Pt:B.P. Text:>85F,>29C
Melt/Freeze Pt:M.P/F.P Text:-130F,-90C
Vapor Pres:360-720
Vapor Density:3-4
Spec Gravity:0.72-0.76
pH:7
Evaporation Rate & Reference:MODERATELY FAST
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS LIQUID; GASOLINE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:BURNING OR EXCESSIVE HEATING MAY
PRODUCE CARBON MONOXIDE AND OTHER HARMFUL GASES/VAPORS.

Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE USER TO
DETERMINE IF THE MATERIAL IS A HAZARDOUS WASTE AT THE TIME OF
DISPOSAL. CHECK BEFORE DISPOSING TO BE SURE YOU ARE IN COMPLIANCE
WITH ALL APPLICABLE LAWS AND REG ULATIONS. CHEMTREC/RCRA EMER.
NO.:800-424-9346

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particular situation.